Reverse osmosis (RO) is a filtration method that removes many types of large molecules and ions from solutions by applying pressure to the solution when it is on one side of a selective membrane. The result is that the solute is retained on the pressurized side of the membrane and the pure solvent is allowed to pass to the other side. To be "selective," this membrane should not allow large molecules or ions through the pores (holes), but should allow smaller components of the solution (such as the solvent) to pass freely.
In the normal osmosis process the solvent naturally moves from an area of low solute concentration, through a membrane, to an area of high solute concentration. The movement of a pure solvent to equalize solute concentrations on each side of a membrane generates a pressure and this is the "osmotic pressure." Applying an external pressure to reverse the natural flow of pure solvent, thus, is reverse osmosis. The process is similar to membrane filtration. However, there are key differences between reverse osmosis and filtration. The predominant removal mechanism in membrane filtration is straining, or size exclusion, so the process can theoretically achieve perfect exclusion of particles regardless of operational parameters such as influent pressure and concentration. Reverse osmosis, however, involves a diffusive mechanism so that separation efficiency is dependent on solute concentration, pressure, and water flux rate. Reverse osmosis is most commonly known for its use in drinking water purification from seawater, removing the salt and other substances from the water molecules.
Applications
Drinking water purification
Marines from Combat Logistics Battalion 31 operate ROWPUs for relief efforts after the 2006 Southern Leyte mudslide
Around the world, household drinking water purification systems, including a reverse osmosis step, are commonly used for improving water for drinking and cooking.
Such systems typically include a number of steps:
a sediment filter to trap particles, including rust and calcium carbonate
optionally, a second sediment filter with smaller pores
an activated carbon filter to trap organic chemicals and chlorine, which will attack and degrade TFC reverse osmosis membranes
a reverse osmosis (RO) filter, which is a thin film composite membrane (TFM or TFC)
optionally, a second carbon filter to capture those chemicals not removed by the RO membrane
optionally an ultra-violet lamp for disinfecting any microbes that may escape filtering by the reverse osmosis membrane
In some systems, the carbon pre filter is omitted, and cellulose triacetate membrane (CTA) is used. The CTA membrane is prone to rotting unless protected by chlorinated water, while the TFC membrane is prone to breaking down under the influence of chlorine. In CTA systems, a carbon postfilter is needed to remove chlorine from the final product, water.
Portable reverse osmosis (RO) water processors are sold for personal water purification in various locations. To work effectively, the water feeding to these units should be under some pressure (40 psi or greater is the norm). Portable RO water processors can be used by people who live in rural areas without clean water, far away from the city's water pipes. Rural people filter river or ocean water themselves, as the device is easy to use (saline water may need special membranes). Some travelers on long boating, fishing, or island camping trips, or in countries where the local water supply is polluted or substandard, use RO water processors coupled with one or more UV sterilizers. RO systems are also now extensively used by marine aquarium enthusiasts. In the production of bottled mineral water, the water passes through an RO water processor to remove pollutants and microorganisms. In European countries, though, such processing of Natural Mineral Water (as defined by a European Directive[4]) is not allowed under European law. In practice, a fraction of the living bacteria can and do pass through RO membranes through minor imperfections, or bypass the membrane entirely through tiny leaks in surrounding seals. Thus, complete RO systems may include additional water treatment stages that use ultraviolet light or ozone to prevent microbiological contamination.
Membrane pore sizes can vary from 0.1 nanometres (3.9×10−9 in) to 5,000 nanometres (0.00020 in) depending on filter type. "Particle filtration" removes particles of 1 micrometre (3.9×10−5 in) or larger. Microfiltration removes particles of 50 nm or larger. "Ultrafiltration" removes particles of roughly 3 nm or larger. "Nanofiltration" removes particles of 1 nm or larger. Reverse osmosis is in the final category of membrane filtration, "hyperfiltration", and removes particles larger than 0.1 nm.
In the United States military, Reverse Osmosis Water Purification Units are used on the battlefield and in training. Capacities range from 1,500 to 150,000 imperial gallons (6,800 to 680,000 l) per day, depending on the need. The most common of these are the 600 and 3,000 gallons per hour units; both are able to purify salt water and water contaminated with chemical, biological, radiological, and nuclear agents from the water. During 24-hour period, at normal operating parameters, one unit can produce 12,000 to 60,000 imperial gallons (55,000 to 270,000 l) of water, with a required 4-hour maintenance window to check systems, pumps, RO elements and the engine generator. A single ROWPU can sustain a force the size of a battalion, or roughly 1,000 to 6,000 servicemembers.
[edit]Water and wastewater purification
Rain water collected from storm drains is purified with reverse osmosis water processors and used for landscape irrigation and industrial cooling in Los Angeles and other cities, as a solution to the problem of water shortages.
In industry, reverse osmosis removes minerals from boiler water at power plants. The water is boiled and condensed repeatedly. It must be as pure as possible so that it does not leave deposits on the machinery or cause corrosion. The deposits inside or outside the boiler tubes may result in under-performance of the boiler, bringing down its efficiency and resulting in poor steam production, hence poor power production at turbine.
It is also used to clean effluent and brackish groundwater. The effluent in larger volumes (more than 500 cu. meter per day) should be treated in an effluent treatment plant first, and then the clear effluent is subjected to reverse osmosis system. Treatment cost is reduced significantly and membrane life of the RO system is increased.
The process of reverse osmosis can be used for the production of deionized water.
RO process for water purification does not require thermal energy. Flow through RO system can be regulated by high pressure pump. The recovery of purified water depend upon various factor including - membrane sizes, membrane pore size, temperature, operating pressure and membrane surface area.
In 2002, Singapore announced that a process named NEWater would be a significant part of its future water plans. It involves using reverse osmosis to treat domestic wastewater before discharging the NEWater back into the reservoirs.
Food Industry
In addition to desalination, reverse osmosis is a more economical operation for concentrating food liquids (such as fruit juices) than conventional heat-treatment processes. Research has been done on concentration of orange juice and tomato juice. Its advantages include a lower operating cost and the ability to avoid heat-treatment processes, which makes it suitable for heat-sensitive substances like the protein and enzymes found in most food products.
Reverse osmosis is extensively used in the dairy industry for the production of whey protein powders and for the concentration of milk to reduce shipping costs. In whey applications, the whey (liquid remaining after cheese manufacture) is concentrated with RO from 6% total solids to 10–20% total solids before UF (ultrafiltration) processing. The UF retentate can then be used to make various whey powders, including whey protein isolate used in bodybuilding formulations. Additionally, the UF permeate, which contains lactose, is concentrated by RO from 5% total solids to 18–22% total solids to reduce crystallization and drying costs of the lactose powder.
Although use of the process was once avoided in the wine industry, it is now widely understood and used. An estimated 60 reverse osmosis machines were in use in Bordeaux, France in 2002. Known users include many of the elite classed growths (Kramer) such as Château Léoville-Las Cases in Bordeaux.
Car Washing
Because of its lower mineral content, reverse osmosis water is often used in car washes during the final vehicle rinse to prevent water spotting on the vehicle. Reverse osmosis is often used to conserve and recycle water within the wash/pre-rinse cycles, especially in drought stricken areas where water conservation is important. Reverse osmosis water also enables the car wash operators to reduce the demands on the vehicle drying equipment, such as air blowers.
Maple Syrup Production
In 1946, some maple syrup producers started using reverse osmosis to remove water from sap before being further boiled down to syrup. The use of reverse osmosis allows approximately 54-42% of the water to be removed from the sap, reducing energy consumption and exposure of the syrup to high temperatures. Microbial contamination and degradation of the membranes has to be monitored.
Hydrogen production
For small scale production of hydrogen, reverse osmosis is sometimes used to prevent formation of minerals on the surface of electrodes.
Reef aquariums
Many reef aquarium keepers use reverse osmosis systems for their artificial mixture of seawater. Ordinary tap water can often contain excessive chlorine, chloramines, copper, nitrogen, phosphates, silicates, or many other chemicals detrimental to the sensitive organisms in a reef environment. Contaminants such as nitrogen compounds and phosphates can lead to excessive, and unwanted, algae growth. An effective combination of both reverse osmosis and deionization (RO/DI) is the most popular among reef aquarium keepers, and is preferred above other water purification processes due to the low cost of ownership and minimal operating costs. Where chlorine and chloramines are found in the water, carbon filtration is needed before the membrane, as the common residential membrane used by reef keepers does not cope with these compounds.
Desalination
Areas that have either no or limited surface water or groundwater may choose to desalinate seawater or brackish water to obtain drinking water. Reverse osmosis is the most common method of desalination, although 85 percent of desalinated water is produced in multistage flash plants.
Large reverse osmosis and multistage flash desalination plants are used in the Middle East, especially Saudi Arabia. The energy requirements of the plants are large, but electricity can be produced relatively cheaply with the abundant oil reserves in the region. The desalination plants are often located adjacent to the power plants, which reduces energy losses in transmission and allows waste heat to be used in the desalination process of multistage flash plants, reducing the amount of energy needed to desalinate the water and providing cooling for the power plant.
Sea Water Reverse Osmosis (SWRO) is a reverse osmosis desalination membrane process that has been commercially used since the early 1970s. Its first practical use was demonstrated by Sidney Loeb and Srinivasa Sourirajan from UCLA in Coalinga, California. Because no heating or phase changes are needed, energy requirements are low in comparison to other processes of desalination, but are still much higher than those required for other forms of water supply (including reverse osmosis treatment of wastewater).[citation needed]
The Ashkelon seawater reverse osmosis (SWRO) desalination plant in Israel is the largest in the world.The project was developed as a BOT (Build-Operate-Transfer) by a consortium of three international companies: Veolia water, IDE Technologies and Elran.
The typical single-pass SWRO system consists of the following components:
Intake
Pretreatment
High pressure pump
Membrane assembly
Remineralisation and pH adjustment
Disinfection
Alarm/control panel
Pretreatment
Pretreatment is important when working with RO and nanofiltration (NF) membranes due to the nature of their spiral wound design. The material is engineered in such a fashion as to allow only one-way flow through the system. As such, the spiral wound design does not allow for backpulsing with water or air agitation to scour its surface and remove solids. Since accumulated material cannot be removed from the membrane surface systems, they are highly susceptible to fouling (loss of production capacity). Therefore, pretreatment is a necessity for any RO or NF system. Pretreatment in SWRO systems has four major components:
Screening of solids: Solids within the water must be removed and the water treated to prevent fouling of the membranes by fine particle or biological growth, and reduce the risk of damage to high-pressure pump components.
Cartridge filtration: Generally, string-wound polypropylene filters are used to remove particles between 1 – 5 micrometres.
Dosing: Oxidizing biocides, such as chlorine, are added to kill bacteria, followed by bisulfite dosing to deactivate the chlorine, which can destroy a thin-film composite membrane. There are also biofouling inhibitors, which do not kill bacteria, but simply prevent them from growing slime on the membrane surface and plant walls.
Prefiltration pH adjustment: If the pH, hardness and the alkalinity in the feedwater result in a scaling tendency when they are concentrated in the reject stream, acid is dosed to maintain carbonates in their soluble carbonic acid form.
CO3−2 + H3O+ = HCO3- + H2O
HCO3- + H3O+ = H2CO3 + H2O
Carbonic acid cannot combine with calcium to form calcium carbonate scale. Calcium carbonate scaling tendency is estimated using the Langelier saturation index. Adding too much sulfuric acid to control carbonate scales may result in calcium sulfate, barium sulfate or strontium sulfate scale formation on the RO membrane.
Prefiltration antiscalants: Scale inhibitors (also known as antiscalants) prevent formation of all scales compared to acid, which can only prevent formation of calcium carbonate and calcium phosphate scales. In addition to inhibiting carbonate and phosphate scales, antiscalants inhibit sulfate and fluoride scales, disperse colloids and metal oxides. Despite claims that antiscalants can inhibit silica formation, there is no concrete evidence to prove that silica polymerization can be inhibited by antiscalants. Antiscalants can control acid soluble scales at a fraction of the dosage required to control the same scale using sulfuric acid .
High pressure pump
The pump supplies the pressure needed to push water through the membrane, even as the membrane rejects the passage of salt through it. Typical pressures for brackish water range from 225 to 375 psi (15.5 to 26 bar, or 1.6 to 2.6 MPa). In the case of seawater, they range from 800 to 1,180 psi (55 to 81.5 bar or 6 to 8 MPa). This requires a large amount of energy.
Membrane assembly
The layers of a membrane.
The membrane assembly consists of a pressure vessel with a membrane that allows feedwater to be pressed against it. The membrane must be strong enough to withstand whatever pressure is applied against it. RO membranes are made in a variety of configurations, with the two most common configurations being spiral-wound and hollow-fiber.
Re mineralization and pH adjustment
The desalinated water is very corrosive and is "stabilized" to protect downstream pipelines and storages, usually by adding lime or caustic to prevent corrosion of concrete lined surfaces. Liming material is used to adjust pH between 6.8 and 8.1 to meet the potable water specifications, primarily for effective disinfection and for corrosion control.
Disinfection
Post-treatment consists of preparing the water for distribution after filtration. Reverse osmosis is an effective barrier to pathogens, however post-treatment provides secondary protection against compromised membranes and downstream problems. Disinfection by means of UV lamps (sometimes called germicidal or bactericidal) may be employed to sterilize pathogens which bypassed the reverse osmosis process. Chlorination or chloramination (chlorine and ammonia) protects against pathogens which may have lodged in the distribution system downstream, such as from new construction, backwash, compromised pipes, etc.
Disadvantages
Household reverse osmosis units use a lot of water because they have low back pressure. As a result, they recover only 5 to 15 percent of the water entering the system. The remainder is discharged as waste water. Because waste water carries with it the rejected contaminants, methods to recover this water are not practical for household systems. Wastewater is typically connected to the house drains and will add to the load on the household septic system. An RO unit delivering 5 gallons of treated water per day may discharge 40 to 90 gallons of wastewater per day.
Large-scale industrial/municipal systems have a production efficiency closer to 48%, because they can generate the high pressure needed for more efficient RO filtration.
New developments
Prefiltration of high fouling waters with another, larger-pore membrane with less hydraulic energy requirement, has been evaluated and sometimes used, since the 1970s. However, this means the water passes through two membranes and is often repressurized, requiring more energy input in the system, increasing the cost.
Other recent development work has focused on integrating RO with electrodialysis to improve recovery of valuable deionized products or minimize concentrate volume requiring discharge or disposal.
References
http://en.wikipedia.org/wiki/Reverse_osmosis
In the normal osmosis process the solvent naturally moves from an area of low solute concentration, through a membrane, to an area of high solute concentration. The movement of a pure solvent to equalize solute concentrations on each side of a membrane generates a pressure and this is the "osmotic pressure." Applying an external pressure to reverse the natural flow of pure solvent, thus, is reverse osmosis. The process is similar to membrane filtration. However, there are key differences between reverse osmosis and filtration. The predominant removal mechanism in membrane filtration is straining, or size exclusion, so the process can theoretically achieve perfect exclusion of particles regardless of operational parameters such as influent pressure and concentration. Reverse osmosis, however, involves a diffusive mechanism so that separation efficiency is dependent on solute concentration, pressure, and water flux rate. Reverse osmosis is most commonly known for its use in drinking water purification from seawater, removing the salt and other substances from the water molecules.
Applications
Drinking water purification
Marines from Combat Logistics Battalion 31 operate ROWPUs for relief efforts after the 2006 Southern Leyte mudslide
Around the world, household drinking water purification systems, including a reverse osmosis step, are commonly used for improving water for drinking and cooking.
Such systems typically include a number of steps:
a sediment filter to trap particles, including rust and calcium carbonate
optionally, a second sediment filter with smaller pores
an activated carbon filter to trap organic chemicals and chlorine, which will attack and degrade TFC reverse osmosis membranes
a reverse osmosis (RO) filter, which is a thin film composite membrane (TFM or TFC)
optionally, a second carbon filter to capture those chemicals not removed by the RO membrane
optionally an ultra-violet lamp for disinfecting any microbes that may escape filtering by the reverse osmosis membrane
In some systems, the carbon pre filter is omitted, and cellulose triacetate membrane (CTA) is used. The CTA membrane is prone to rotting unless protected by chlorinated water, while the TFC membrane is prone to breaking down under the influence of chlorine. In CTA systems, a carbon postfilter is needed to remove chlorine from the final product, water.
Portable reverse osmosis (RO) water processors are sold for personal water purification in various locations. To work effectively, the water feeding to these units should be under some pressure (40 psi or greater is the norm). Portable RO water processors can be used by people who live in rural areas without clean water, far away from the city's water pipes. Rural people filter river or ocean water themselves, as the device is easy to use (saline water may need special membranes). Some travelers on long boating, fishing, or island camping trips, or in countries where the local water supply is polluted or substandard, use RO water processors coupled with one or more UV sterilizers. RO systems are also now extensively used by marine aquarium enthusiasts. In the production of bottled mineral water, the water passes through an RO water processor to remove pollutants and microorganisms. In European countries, though, such processing of Natural Mineral Water (as defined by a European Directive[4]) is not allowed under European law. In practice, a fraction of the living bacteria can and do pass through RO membranes through minor imperfections, or bypass the membrane entirely through tiny leaks in surrounding seals. Thus, complete RO systems may include additional water treatment stages that use ultraviolet light or ozone to prevent microbiological contamination.
Membrane pore sizes can vary from 0.1 nanometres (3.9×10−9 in) to 5,000 nanometres (0.00020 in) depending on filter type. "Particle filtration" removes particles of 1 micrometre (3.9×10−5 in) or larger. Microfiltration removes particles of 50 nm or larger. "Ultrafiltration" removes particles of roughly 3 nm or larger. "Nanofiltration" removes particles of 1 nm or larger. Reverse osmosis is in the final category of membrane filtration, "hyperfiltration", and removes particles larger than 0.1 nm.
In the United States military, Reverse Osmosis Water Purification Units are used on the battlefield and in training. Capacities range from 1,500 to 150,000 imperial gallons (6,800 to 680,000 l) per day, depending on the need. The most common of these are the 600 and 3,000 gallons per hour units; both are able to purify salt water and water contaminated with chemical, biological, radiological, and nuclear agents from the water. During 24-hour period, at normal operating parameters, one unit can produce 12,000 to 60,000 imperial gallons (55,000 to 270,000 l) of water, with a required 4-hour maintenance window to check systems, pumps, RO elements and the engine generator. A single ROWPU can sustain a force the size of a battalion, or roughly 1,000 to 6,000 servicemembers.
[edit]Water and wastewater purification
Rain water collected from storm drains is purified with reverse osmosis water processors and used for landscape irrigation and industrial cooling in Los Angeles and other cities, as a solution to the problem of water shortages.
In industry, reverse osmosis removes minerals from boiler water at power plants. The water is boiled and condensed repeatedly. It must be as pure as possible so that it does not leave deposits on the machinery or cause corrosion. The deposits inside or outside the boiler tubes may result in under-performance of the boiler, bringing down its efficiency and resulting in poor steam production, hence poor power production at turbine.
It is also used to clean effluent and brackish groundwater. The effluent in larger volumes (more than 500 cu. meter per day) should be treated in an effluent treatment plant first, and then the clear effluent is subjected to reverse osmosis system. Treatment cost is reduced significantly and membrane life of the RO system is increased.
The process of reverse osmosis can be used for the production of deionized water.
RO process for water purification does not require thermal energy. Flow through RO system can be regulated by high pressure pump. The recovery of purified water depend upon various factor including - membrane sizes, membrane pore size, temperature, operating pressure and membrane surface area.
In 2002, Singapore announced that a process named NEWater would be a significant part of its future water plans. It involves using reverse osmosis to treat domestic wastewater before discharging the NEWater back into the reservoirs.
Food Industry
In addition to desalination, reverse osmosis is a more economical operation for concentrating food liquids (such as fruit juices) than conventional heat-treatment processes. Research has been done on concentration of orange juice and tomato juice. Its advantages include a lower operating cost and the ability to avoid heat-treatment processes, which makes it suitable for heat-sensitive substances like the protein and enzymes found in most food products.
Reverse osmosis is extensively used in the dairy industry for the production of whey protein powders and for the concentration of milk to reduce shipping costs. In whey applications, the whey (liquid remaining after cheese manufacture) is concentrated with RO from 6% total solids to 10–20% total solids before UF (ultrafiltration) processing. The UF retentate can then be used to make various whey powders, including whey protein isolate used in bodybuilding formulations. Additionally, the UF permeate, which contains lactose, is concentrated by RO from 5% total solids to 18–22% total solids to reduce crystallization and drying costs of the lactose powder.
Although use of the process was once avoided in the wine industry, it is now widely understood and used. An estimated 60 reverse osmosis machines were in use in Bordeaux, France in 2002. Known users include many of the elite classed growths (Kramer) such as Château Léoville-Las Cases in Bordeaux.
Car Washing
Because of its lower mineral content, reverse osmosis water is often used in car washes during the final vehicle rinse to prevent water spotting on the vehicle. Reverse osmosis is often used to conserve and recycle water within the wash/pre-rinse cycles, especially in drought stricken areas where water conservation is important. Reverse osmosis water also enables the car wash operators to reduce the demands on the vehicle drying equipment, such as air blowers.
Maple Syrup Production
In 1946, some maple syrup producers started using reverse osmosis to remove water from sap before being further boiled down to syrup. The use of reverse osmosis allows approximately 54-42% of the water to be removed from the sap, reducing energy consumption and exposure of the syrup to high temperatures. Microbial contamination and degradation of the membranes has to be monitored.
Hydrogen production
For small scale production of hydrogen, reverse osmosis is sometimes used to prevent formation of minerals on the surface of electrodes.
Reef aquariums
Many reef aquarium keepers use reverse osmosis systems for their artificial mixture of seawater. Ordinary tap water can often contain excessive chlorine, chloramines, copper, nitrogen, phosphates, silicates, or many other chemicals detrimental to the sensitive organisms in a reef environment. Contaminants such as nitrogen compounds and phosphates can lead to excessive, and unwanted, algae growth. An effective combination of both reverse osmosis and deionization (RO/DI) is the most popular among reef aquarium keepers, and is preferred above other water purification processes due to the low cost of ownership and minimal operating costs. Where chlorine and chloramines are found in the water, carbon filtration is needed before the membrane, as the common residential membrane used by reef keepers does not cope with these compounds.
Desalination
Areas that have either no or limited surface water or groundwater may choose to desalinate seawater or brackish water to obtain drinking water. Reverse osmosis is the most common method of desalination, although 85 percent of desalinated water is produced in multistage flash plants.
Large reverse osmosis and multistage flash desalination plants are used in the Middle East, especially Saudi Arabia. The energy requirements of the plants are large, but electricity can be produced relatively cheaply with the abundant oil reserves in the region. The desalination plants are often located adjacent to the power plants, which reduces energy losses in transmission and allows waste heat to be used in the desalination process of multistage flash plants, reducing the amount of energy needed to desalinate the water and providing cooling for the power plant.
Sea Water Reverse Osmosis (SWRO) is a reverse osmosis desalination membrane process that has been commercially used since the early 1970s. Its first practical use was demonstrated by Sidney Loeb and Srinivasa Sourirajan from UCLA in Coalinga, California. Because no heating or phase changes are needed, energy requirements are low in comparison to other processes of desalination, but are still much higher than those required for other forms of water supply (including reverse osmosis treatment of wastewater).[citation needed]
The Ashkelon seawater reverse osmosis (SWRO) desalination plant in Israel is the largest in the world.The project was developed as a BOT (Build-Operate-Transfer) by a consortium of three international companies: Veolia water, IDE Technologies and Elran.
The typical single-pass SWRO system consists of the following components:
Intake
Pretreatment
High pressure pump
Membrane assembly
Remineralisation and pH adjustment
Disinfection
Alarm/control panel
Pretreatment
Pretreatment is important when working with RO and nanofiltration (NF) membranes due to the nature of their spiral wound design. The material is engineered in such a fashion as to allow only one-way flow through the system. As such, the spiral wound design does not allow for backpulsing with water or air agitation to scour its surface and remove solids. Since accumulated material cannot be removed from the membrane surface systems, they are highly susceptible to fouling (loss of production capacity). Therefore, pretreatment is a necessity for any RO or NF system. Pretreatment in SWRO systems has four major components:
Screening of solids: Solids within the water must be removed and the water treated to prevent fouling of the membranes by fine particle or biological growth, and reduce the risk of damage to high-pressure pump components.
Cartridge filtration: Generally, string-wound polypropylene filters are used to remove particles between 1 – 5 micrometres.
Dosing: Oxidizing biocides, such as chlorine, are added to kill bacteria, followed by bisulfite dosing to deactivate the chlorine, which can destroy a thin-film composite membrane. There are also biofouling inhibitors, which do not kill bacteria, but simply prevent them from growing slime on the membrane surface and plant walls.
Prefiltration pH adjustment: If the pH, hardness and the alkalinity in the feedwater result in a scaling tendency when they are concentrated in the reject stream, acid is dosed to maintain carbonates in their soluble carbonic acid form.
CO3−2 + H3O+ = HCO3- + H2O
HCO3- + H3O+ = H2CO3 + H2O
Carbonic acid cannot combine with calcium to form calcium carbonate scale. Calcium carbonate scaling tendency is estimated using the Langelier saturation index. Adding too much sulfuric acid to control carbonate scales may result in calcium sulfate, barium sulfate or strontium sulfate scale formation on the RO membrane.
Prefiltration antiscalants: Scale inhibitors (also known as antiscalants) prevent formation of all scales compared to acid, which can only prevent formation of calcium carbonate and calcium phosphate scales. In addition to inhibiting carbonate and phosphate scales, antiscalants inhibit sulfate and fluoride scales, disperse colloids and metal oxides. Despite claims that antiscalants can inhibit silica formation, there is no concrete evidence to prove that silica polymerization can be inhibited by antiscalants. Antiscalants can control acid soluble scales at a fraction of the dosage required to control the same scale using sulfuric acid .
High pressure pump
The pump supplies the pressure needed to push water through the membrane, even as the membrane rejects the passage of salt through it. Typical pressures for brackish water range from 225 to 375 psi (15.5 to 26 bar, or 1.6 to 2.6 MPa). In the case of seawater, they range from 800 to 1,180 psi (55 to 81.5 bar or 6 to 8 MPa). This requires a large amount of energy.
Membrane assembly
The layers of a membrane.
The membrane assembly consists of a pressure vessel with a membrane that allows feedwater to be pressed against it. The membrane must be strong enough to withstand whatever pressure is applied against it. RO membranes are made in a variety of configurations, with the two most common configurations being spiral-wound and hollow-fiber.
Re mineralization and pH adjustment
The desalinated water is very corrosive and is "stabilized" to protect downstream pipelines and storages, usually by adding lime or caustic to prevent corrosion of concrete lined surfaces. Liming material is used to adjust pH between 6.8 and 8.1 to meet the potable water specifications, primarily for effective disinfection and for corrosion control.
Disinfection
Post-treatment consists of preparing the water for distribution after filtration. Reverse osmosis is an effective barrier to pathogens, however post-treatment provides secondary protection against compromised membranes and downstream problems. Disinfection by means of UV lamps (sometimes called germicidal or bactericidal) may be employed to sterilize pathogens which bypassed the reverse osmosis process. Chlorination or chloramination (chlorine and ammonia) protects against pathogens which may have lodged in the distribution system downstream, such as from new construction, backwash, compromised pipes, etc.
Disadvantages
Household reverse osmosis units use a lot of water because they have low back pressure. As a result, they recover only 5 to 15 percent of the water entering the system. The remainder is discharged as waste water. Because waste water carries with it the rejected contaminants, methods to recover this water are not practical for household systems. Wastewater is typically connected to the house drains and will add to the load on the household septic system. An RO unit delivering 5 gallons of treated water per day may discharge 40 to 90 gallons of wastewater per day.
Large-scale industrial/municipal systems have a production efficiency closer to 48%, because they can generate the high pressure needed for more efficient RO filtration.
New developments
Prefiltration of high fouling waters with another, larger-pore membrane with less hydraulic energy requirement, has been evaluated and sometimes used, since the 1970s. However, this means the water passes through two membranes and is often repressurized, requiring more energy input in the system, increasing the cost.
Other recent development work has focused on integrating RO with electrodialysis to improve recovery of valuable deionized products or minimize concentrate volume requiring discharge or disposal.
References
http://en.wikipedia.org/wiki/Reverse_osmosis
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